Inherent electrochemical activity of TiO2 (anatase,rutile) enhances the charge capacity of cathodes of lithium-sulfur batteries

Journal of Solid State Electrochemistry - The addition of nanocrystalline titanium dioxide (P90) to a cathode of Li/S cell enhances its voltammetric charge capacity by 19%, from which only a small...     

Inverse central ordering for the Newton interpolation formula

Numerical Algorithms - An inverse central ordering of the nodes is proposed for the Newton interpolation formula. This ordering may improve the stability for certain distributions of nodes. For...     

Hospital preparedness during epidemics using simulation: the case of COVID-19

Central European Journal of Operations Research - This paper presents a discrete event simulation model to support decision-making for the short-term planning of hospital resource needs, especially...     

Diffusion Model of a Non-Integer Order PIγ Controller with TCP/UDP Streams

In this article, a way to employ the diffusion approximation to model interplay between TCP and UDP flows is presented. In order to control traffic congestion, an environment of IP routers applying AQM (Active Queue Management) algorithms has been introduced. Furthermore, the impact of the fractional controller PIγ and its parameters on the transport protocols is investigated. The controller has been elaborated in accordance with the control theory. The TCP and UDP flows are transmitted simultaneously and are mutually independent. Only the TCP is controlled by the AQM algorithm. Our diffusion model allows a single TCP or UDP flow to start or end at any time, which distinguishes it from those previously described in the literature.     

Morita Invariance for Infinitesimal Deformations

Algebras and Representation Theory - Let A and B be two Morita equivalent finite dimensional associative algebras over a field ��. It is well known that Hochschild cohomology is...     

Two-Photon Absorption Enhancement by the Inclusion of a Tropone Ring in Distorted Nanographene Ribbons

A new family of distorted ribbon-shaped nanographenes was designed, synthesized, and their optical and electrochemical properties were evaluated, pointing out an unprecedented correlation between their structural characteristics and the two-photon absorption (TPA) responses and electrochemical band gaps. Three nanographene ribbons have been prepared: a seven-membered-ring-containing nanographene presenting a tropone moiety at the edge, its full-carbon analogue, and a purely hexagonal one. We have found that the TPA cross-sections and the electrochemical band gaps of the seven-membered-ring-containing compounds are higher and lower, respectively, than those of the fully hexagonal polycyclic aromatic hydrocarbon (PAH). Interestingly, the inclusion of additional curvature has a positive effect in terms of non-linear optical properties of those ribbons.     

On cardinal characteristics of Yorioka ideals

Yorioka introduced a class of ideals (parametrized by reals) on the Cantor space to prove that the relation between the size of the continuum and the cofinality of the strong measure zero ideal on the real line cannot be decided in . We construct a matrix iteration of c.c.c. posets to force that, for many ideals in that class, their associated cardinal invariants (i.e., additivity, covering, uniformity and cofinality) are pairwise different. In addition, we show that, consistently, the additivity and cofinality of Yorioka ideals does not coincide with the additivity and cofinality (respectively) of the ideal of Lebesgue measure zero subsets of the real line.     

An unexpected Pummerer rearrangement in the synthetic route to ethyl (2′-hydroxy-4′,5′-methylenedioxyphenyl)acetate: An alternative approach to 2,3-dimethylthio benzofurans

The synthesis of ethyl (2′-hydroxy-4′,5′-methylendioxophenyl)acetate, a fragment of the antihyperglycemic natural coumarin subcoriacin, is reported. We found an expeditious route to the title compound in five steps. Final metal catalyzed acid ethanolysis of the vinylic 1,1-methylthio methylsulfoxide derivative afforded the required aryl acetic ester, but in the absence of metal catalyst, an unexpected Pummerer rearrangement produced the 2,3-dimethylthiofuran derivative as the major product. This last result provides an alternative entry to 2,3-dimethlythiobenzofurans.     

Reversible Activation of Water by an Air- and Moisture-Stable Frustrated Rhodium Nitrogen Lewis Pair

[Cp*Rh(κ³N,N′,P- L )][SbF₆] (Cp*=C₅Me₅), bearing a guanidine-derived phosphano ligand L , behaves as a “dormant” frustrated Lewis pair and activates H₂ and H₂O in a reversible manner. When D₂O is employed, a facile H/D exchange at the Cp* ring takes place through sequential C(sp³)−H bond activation.     

Nanostructuring of 1-butyl-4-methylpyridinium chloride in ionic liquid–iron oxide nanofluids

Journal of Thermal Analysis and Calorimetry - Understanding the behavior of ionic liquids (ILs) in ionic liquid-based nanofluids has great significance for its proper application. The phase changes...